If you use the fittings every so often, you should not need to do anything to keep them moving freely. Each time you connect or disconnect a hose from the fitting, usually a few drops of hydraulic fluid seeps out onto the fitting and that is usually enough to keep them freed up - - unless the machine sits out in the rain and snow all the time and the fluid repeatedly gets washed off. Dust, dirt and sand tend to stick oily or greased areas so if you ever do need to lubricate them, use a vey light oil that does not become sticky.
The best advice I can give is to use them regularly and keep them dry from water and snow or at least work them by hand and lightly oiled every couple months if you are worried about them rusting up. Purchase dust caps for your tractor and attachment fittings if you don't have them. They keep the internals of the tractor fittings and external surfaces of the attachment fittings clean and protects from dirt contamination.
The best advice I can give is to use them regularly and keep them dry from water and snow or at least work them by hand and lightly oiled every couple months if you are worried about them rusting up. Purchase dust caps for your tractor and attachment fittings if you don't have them. They keep the internals of the tractor fittings and external surfaces of the attachment fittings clean and protects from dirt contamination.